Let $w=u+iv$ and $z=x+iy$ with $u,v,x,y\in\mathbb{R}$. Is the function $$f:\, \mathbb{C}\to\mathbb{C},\, f(z)=e^x\cos y+ie^x\sin y$$ the only solution of the functional equation $$f:\, \mathbb{C}\to\mathbb{C},\, f(w+z)=f(w)f(z),\, f(1)=e?$$
I was only able to prove that it is a solution: $f(1)=e$ trivially and $$\begin{align}f(w)f(z)&=(e^u\cos v+ie^u\sin v)(e^x\cos y+ie^x\sin y)\\&=e^{u+x}(\cos v\cos y-\sin v\sin y)+ie^{u+x}(\sin v\cos y+\cos v\sin y)\\&=e^{u+x}\cos (v+y)+ie^{u+x}\sin (v+y)\\&=f(w+z).\end{align}$$
Without any additional assumption the answer is no, it's not the only solution. Consider for example $f(z)=e^{\overline{z}}$, or in your terms $f(z)=e^x\cos y-ie^x\sin y$. Another example could be $f(z)=e^{\Re(z)}$ (or $f(z)=e^x$), I guess you get the idea.
If you add an assumption for $f$ to be holomorphic (for example) then the solution is unique, see Find the holomorphic function satisfying an equation and agrees with $e^x$ in real line.