This is the problem 5.53 of Rotman, Homological Algebra.
In any category having a zero object calling it $0$, prove that every kernel is monomorphism.
Let $f:A\to B$ and $\ker(f):K\to A$ be the kernel. Any $g:X\to K$, $f\circ \ker(f)\circ g=0$. In sum, I have
$\begin{array} KK & \stackrel{\ker(f)}{\longrightarrow} & A & \stackrel{f}{\longrightarrow} B\\ \uparrow{g}\\ X \end{array}$
I can choose $X=0$ here. If there is $\ker(\ker(f)):K'\to K$, then there is a unique $0$-map $0_{K'}:0\to K'$. Since $0$ is zero object, I can reverse the arrow. However, it is not clear why the diagram commutes for $K'\to 0\to K$ which is $0\in\mathrm{Hom}(K',K)$ compatible with $K'\to K$.
How do I know that I can reverse arrow?
Is there a way to show $K'$ being both initial and final in the category?
The kernel is the equaliser of $f$ and the zero map from $A$ to $B$ (that factoring through the zero object). All equaliser maps (in any category) are monic.