Approximate largest (in quantity, not magnitude) eigenvalue and eigenvector of a matrix

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I need to obtain an approximate expression for the eigenvector corresponding to the largest real eigenvalue of a matrix, as well as the largest eigenvalue. Note that I mean largest not in absolute value, but largest in real value. The matrix can be approximately diagonal in some cases, but not always.

I have tried perturbation theory but it is not working very well. Are there other approximation schemes for the eigenvalues and eigenvectors of a matrix that I can try?