I know of Conway's use of ordinals to exhibit the algebraic closure of $\mathcal{F}_2$. I also read a document about the Cantor Bendixson rank of some family of groups. But I found no applications of ordinals outside Ordinal Analysis that use "big" ordinals. In particular, no applications that make explicit use of notation systems like Veblen or Bachmann (or stronger). Are there any?
Edit: I already got useful answers (in the comments) in computability theory and in topology. However, I'll leave the answer open because I'm interesting in getting as many nice applications as possible.
I'm particularly interested in applications in "less abstract" branches of mathematics and, I explained earlier, in an explicit use of ordinal notations.
How about googology? Pretty much all of this field is dedicated to creating bigger numbers than anyone else. And there are methods that people have used ordinals for to create numbers. I’m going to quickly explain the fast growing hierarchy as an example.
We can see how useful this would be for creating large numbers, as using large ordinals, like the Bachman-Howard ordinal would lead to extremely large numbers being created. Also, just in case you didn’t get my explanation of it, go to https://en.m.wikipedia.org/wiki/Fast-growing_hierarchy for a better explanation.
This is one (absolutely pointless, yet fun) use for large countable ordinals.
Although, this doesn’t just work for countable ordinals, it would work for ordinals such as $\omega_1$ too, if our mortal minds could comprehend its canonical sequence...