The Classical open mapping theorem for Banach spaces tells that if $T:X \to Y$ is a continuous surjective linear map, then it is open.
I have attempted to essentially "adapt" the proof for Lie groups:
Let $G,H$ be connected Lie groups (embedded in $\mathbb R^n$, I've used second-countability and completeness so far). If $\phi: G \to H$ is a surjective Lie group homomorphism, then the image of an open neighborhood $U$ of the identity in $G$ is again a neighborhood with nonempty interior about $1 \in H$.
Pick some neighborhood $U$ of $1 \in G$. We want to pick some open ball $V$in $U$ so that the closure of $V$ is compact and contained in $U$. Hence,
$$G=\{x V \mid x \in G\}$$
but we can choose countably many such $x \in G$. We can call this collection $\{x_n\}$, and consider the image of $G$ under $\phi$, which is all of $H$. In particular, $H:=\{\phi(x_n \overline{V}) \mid n \in \mathbb N\}$. But since $\phi$ is a homomorphism, this is the same thing as considering a whole bunch of $\phi(x_n)\phi(\overline{V})$, whose images are compact and hence closed. By Baire category, one of these guys has empty interior, say $\phi(x_n)\phi(\overline{V})$. But then $\phi(\overline{V})$ has nonempty interior, since multiplication by an element is a homeomorphism. But then $\phi(U)$ has nonempty interior.
From here, one can finish by first showing that this implies that there is a basis $\mathcal U$ about the origin so that the image of each element contains the identity in $H$, which is sufficient to show the main theorem, since we can then use the homomorphism property to show that for every open set $W$ about $w \in G$, the image $f(w) \in \mathrm{Int}(W)$, proving the theorem.
Is My proof correct?
I've seen one reference "An Open Mapping Theorem for Topological Groups". but this ultimately just redirects to a source that I cannot find. Is there a better way to show this Theorem? I'm not looking for maximal generality (weakest hypotheses) just yet, only to understand why this theorem might be true.
A sufficient answer in my eyes is either a convincing argument for why my proof fails (including something in the way of "is this idea recoverable?") or some affirmation that it is indeed correct.
When you have an action of a topological group $K$ over a space $X$, the quotient $X \to X/K$ is an open map. This is very easy to prove.
Now let $K$ be the kernel of your surjective map $\phi \colon G \to H$. The group $K$ acts on $G$ by multiplication on the right and the quotient is $G/K$. The map $\phi$ factors through a group homomorphism $ \bar{\phi} \colon G/K \to H$ which is bijective and continuous. If this map is open (hence an isomorphism of topological groups), then $\phi$ is open. So another way of looking at your question is, does the first isomorphism theorem hold for connected Lie groups?
The answer is yes and one proof goes along the following lines:
1) The quotient $ G \to G/K$ is a submersion.
2) If $\phi$ is smooth, so is $\bar{\phi}$.
3) An injective homomorphism of Lie groups must be an immersion.
4) The map $\bar{\phi}$ is a submersion and an immersion, so it is a local diffeomorphism, hence a diffeomorphism and so an isomorphism of topological groups.
This is essentially the proof of Theorem 17.4 in
https://www.staff.science.uu.nl/~ban00101/lie2016/lie2010.pdf
I could not see any flaw in your proof. I am not sure if you find that this way is better, but I found more intuitive to think about it in terms of the first isomorphism theorem (which does not hold in general for general topological groups).