Let $P_{k,j}$ be the probability that a simple symmetric random walk starting from the origin reaches the point $k \in \mathbb{N}$ precisely in $j$ steps without ever returning to the origin. Obviously, $P_{k,j}>0$ if and only if $j \geq k$. Let $ 0<c <1$ be a constant.
Is there a way to rewrite the following sum in a "nicer" way, without computing $P_{k,j}$ explicitly, by using the properties of simple symmetric random walk?
$$ \sum_{k=1}^{\infty} \sum_{j=k}^{\infty} P_{k,j} \, \, c^{j-1}$$
Let $P_{k,j}$ be the probability that you reach $k\ge 1$ in exactly $j$ steps without ever returning to the origin. As OP points out, $P_{k,j}=0$ for $j<k$, so the sum $$ S=\sum_{k=1}^{\infty}\sum_{j=k}^{\infty}P_{k,j}c^{j-1}=\sum_{k=1}^{\infty}\sum_{j=1}^{\infty}P_{k,j}c^{j-1}=\sum_{j=1}^{\infty}\left(\sum_{k=1}^{\infty}P_{k,j}\right)c^{j-1}. $$ That is, the sum over $k$ can be carried out first. The term inside the parentheses is just half the probability that the walk has never returned to the origin after $j$ steps. The probability that a random walk of length $j$ is non-recurrent is given by $1 - 2^{-j}R_{j}$, where $R_j$ is the number of walks of length $j$ that have returned to the origin. So $$ S=\frac{1}{2}\sum_{j=1}^{\infty}\left(1 - 2^{-j}R_j\right) c^{j-1} = \frac{1}{2(1-c)}-\frac{1}{4}\sum_{j=1}^{\infty}\left(\frac{c}{2}\right)^{j-1}R_j. $$ Now, the number of recurrent walks of length $j$ is equal to the sum over $T \le j$ of the number of walks that first return to the origin after $j$ steps, times $2^{j-T}$. We can restrict the sum to even $T=2n+2$: as is well known, the number of walks that first return to the origin after $2n+2$ steps is given by twice the $n$-th Catalan number. So $$ R_j=\sum_{n=0}^{\lfloor j/2\rfloor - 1} 2^{j-2n-2} (2C_n)=2^j\sum_{n=0}^{\lfloor j/2\rfloor - 1} \frac{2^{-2n-1}}{n+1}{{2n}\choose{n}}=2^j\left(1-2^{-2\lfloor{j/2}\rfloor}{{2\lfloor{j/2}\rfloor}\choose{\lfloor{j/2}\rfloor}}\right)\\=2^j-2^{\lceil{j/2}\rceil - \lfloor{j/2}\rfloor}{{2\lfloor{j/2}\rfloor}\choose{\lfloor{j/2}\rfloor}}. $$ So for even $j=2k$, we have $$ R_{2k}=2^{2k}-{{2k}\choose{k}}, $$ while for odd $j=2k+1$, we have $$ R_{2k+1}=2^{2k+1}-2{{2k}\choose{k}}=2 R_{2k}. $$ Then $$ \sum_{j=1}^{\infty}\left(\frac{c}{2}\right)^{j-1}R_j = \sum_{k=1}^{\infty}\left(\frac{c}{2}\right)^{2k-1}\left(R_{2k}+\frac{c}{2}R_{2k+1}\right)=(1+c)\sum_{k=1}^{\infty}\left(\frac{c}{2}\right)^{2k-1}\left(2^{2k}-{{2k}\choose{k}}\right)\\=(1+c)\sum_{k=1}^{\infty}2c^{2k-1}-(1+c)\sum_{k=1}^{\infty}\left(\frac{c}{2}\right)^{2k-1}{{2k}\choose{k}} \\ =\frac{2c(1+c)}{1-c^2}-\frac{2(1+c)}{c}\left(\frac{1}{\sqrt{1-c^2}}-1\right)=\frac{2c}{1-c}+\frac{2(1+c)}{c}-\frac{2}{c}\sqrt{\frac{1+c}{1-c}}. $$ Putting it all together, we have $$ S=\frac{1}{2(1-c)}-\frac{c}{2(1-c)}-\frac{1+c}{2c}+\frac{1}{2c}\sqrt{\frac{1+c}{1-c}}=\frac{1}{2c}\left(-1 + \sqrt{\frac{1+c}{1-c}}\right). $$