I have this simple exercise to do and I'm new to this topic.
Seeing the slides of my professor, I would solve the problem in this way:
$E(Y)=c_1 μ_1+c_2 μ_2$
$E(Y)=-54.2424$
$Var(Y)=σ_{22}$
$Var(Y)=0.65$
I don't have the solutions so I take this opportunity to know if my reasoning has errors or not. If there are, how should I proceed to solve it?

Your expression for $E(Y)$ is correct. The variance of $Y$ won't be $\sigma_{22}$ - that is the variance of $X_2$. For the variance of $Y$ use the equation
$$Var(Y) = Var(c_1 X_1 + c_2 X_2) = c_1^2 Var(X_1) + c_2^2 Var(X_2) + 2c_1 c_2 Cov(X_1,X_2)$$
which is the general equation for the variance of a linear combination of two random variables.