Brauer group of a field of rational numbers

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Can we say anything about Brauer group of $\mathbb{Q}$? And how can we construct it?

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The Brauer group of $\mathbb{Q}$ can be identified with a subgroup of $\bigoplus_vBr(\mathbb{Q}_v)$, the direct sum taken over all places of $\mathbb{Q}$ (including the Archimedean one). The map from $Br(\mathbb{Q})$ into this direct sum is given by tensoring any central simple algebra representing a class of the Brauer group with all the completions, to get central simple algebras over the completions. This tensor product will be a split CSA for almost all $v$, so you do land in the direct sum, rather than in the direct product.

Each of the local Brauer groups at the finite places is isomorphic to $\mathbb{Q}/\mathbb{Z}$, while $Br(\mathbb{R})\cong\frac12\mathbb{Z}/\mathbb{Z}$, the isomorphism given by the Hasse invariant. From the direct sum, you have a map to $\mathbb{Q}/\mathbb{Z}$ that simply adds the Hasse invariants, and the Brauer group of $\mathbb{Q}$ in the direct sum is precisely the kernel of this map.

A source for all of this would be, for example, the book on algebraic number theory edited by Cassels and Froehlich, specifically the chapters on local and global class field theory.

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$\DeclareMathOperator{\br}{Br}$ This can be done using the Brauer-Hasse-Noether theorem. One statement of this theorem is that for $k$ a global field, there is a canonical exact sequence $$ 0 \to \br(k) \to \bigoplus_v \br(k_v) \to \mathbb Q/\mathbb Z \to 0 . $$ where $v$ ranges over all places (finite and infinite) of $k$. It is known (see for example Serre's Local Fields, chapter 13) that $\br(k_v)\simeq \mathbb Q/\mathbb Z$. So for $k=\mathbb Q$, our sequence is $$ 0 \to \br(\mathbb Q) \to \mathbb Z/2\times \bigoplus_p \mathbb Q/\mathbb Z \to \mathbb Q/\mathbb Z\to 0. $$ So we have $$ \br(\mathbb Q) = \left\{(a,x):a\in \{0,1/2\}\text{ , }x\in \bigoplus_p \mathbb Q/\mathbb Z\text{ and }a+\sum x_p=0\right\}. $$ We have similar descriptions of $\br(k)$ for any global field $k$.

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The Brauer group of $\mathbb Q$ (and more generally, of any finite extension of $\mathbb Q$) is described by class field theory.

The answer is that it is isomorphic to the direct sum of $\mathbb Z/2 \mathbb Z$ and a countable number of copies of $\mathbb Q/\mathbb Z$.

More canonically, consider the direct sum $$\dfrac{1}{2}\mathbb Z/\mathbb Z \oplus \bigoplus_p \mathbb Q/\mathbb Z,$$ where $\dfrac{1}{2}\mathbb Z/\mathbb Z$ denotes the (unique) cyclic subgroup of order $2$ in $\mathbb Q/\mathbb Z$, and the direct sum is indexed by primes.

There is a natural map from this direct sum to $\mathbb Q/\mathbb Z$, given by summing components, and the Brauer group of $\mathbb Q$ is canonically identified with its kernel.

The elements of order $2$ correspond to quaternion algebras over $\mathbb Q$, and these are constructed explicitly in Serre's book A course in arithmetic.

Off the top of my head I'm not sure about computing them explicitly more generally.

[Note: I wrote this answer several hours ago, but just got around to submitting it now. Thus it likely duplicates the other answers.]