We know the Stone-Čech compactification $(h, \beta X)$ of a Tychonoff space $X$ is its largest (in particular, a maximal) Hausdorff compactification, in the sense that if $(k,\gamma X$) is any other Hausdorff compactification, then there is a continuous map $f:\beta X \rightarrow \gamma X$ such that $fh=k$.
What about if I restrict to considering just all metrizable Hausdorff compactifications? To fix ideas, say $X$ is a noncompact metric space. (In particular $\beta X$ will not be metrizable.) Is there a maximal metrizable Hausdorff compactification of $X$?
I am guessing no: if we're given any metrizable Hausdorff compactification of noncompact metric space $X$, we can make another metrizable Hausdorff compactification that is larger (in the sense of the first paragraph above).
No. Let $X$ be a noncompact metric space and let $Y$ be a metrizable compactification of $X$. Pick a point $y\in Y$ and a sequence $(x_n)$ of distinct points in $X$ converging to $y$. Let $A$ consist of the points $x_n$ for all even $n$ and let $B$ consist of the points $x_n$ for all odd $n$. Then $A$ and $B$ are closed and disjoint in $X$, so there exists a continuous $f:X\to[0,1]$ such that $f$ maps $A$ to $0$ and $B$ to $1$. This map $f$ does not extend continuously to $Y$.
We can now embed $X$ in $Y\times [0,1]$ by using the given embedding $X\to Y$ on the first coordinate and $f$ on the second coordinate. The closure of the image of $X$ in $Y\times[0,1]$ is then a metrizable compactification of $X$, which is strictly larger than $Y$ since $f$ extends continuously to it.
For another perspective on this, note that the algebra $C_b(X)$ of bounded continuous functions on $X$ can canonically be identified with $C(\beta X)$, and an arbitrary compactification of $X$ just corresponds to a closed subalgebra of $C_b(X)$ which separates points from closed sets on $X$. Moreover, a compactification is metrizable iff the corresponding subalgebra is separable. "Larger" compactifications in your sense just corresponds to the inclusion order on subalgebras.
So, given any metrizable compactification corresponding to a separable subalgebra $C(Y)\subset C_b(X)$, you can get a larger separable subalgebra by just taking some $f\in C_b(X)\setminus C(Y)$ and taking the closed subalgebra generated by $f$ and $C(Y)$.