One of the nicer consequences of compactness is that there is no statement in first-order logic whose content "$\leq$ is a well-order". So we can show that there are countable structure $(M,\leq)$ which are elementarily equivalent to $\Bbb N$, but not isomorphic to it.
What about adding $S,+,\cdot$ and $0$? Well. Also not very good. The theory of the structure $(\Bbb N,0,S,+,\cdot,\leq)$ has $2^{\aleph_0}$ non-isomorphic countable models. This shows that none of these additions get us any closer to finding an $\aleph_0$-categorical theory for $\Bbb N$.
Question. Is there a finite (or countable if needed) first-order language which includes $\leq$, and an $\aleph_0$-categorical theory $T$ whose countable structure is order isomorphic to $(\Bbb N,\leq)$?
Take countably many functions and relations on $\mathbb{N}$. Add a symbol for each, together with all sentences that are true in $\mathbb{N}$ under the natural interpretation. Let the resulting theory be $T$. In the usual way we can use the Compactness Theorem and Downward Loweheim-Skolem to find a countable model of $T$ that is not isomorphic to $\mathbb{N}$.