How do I see whether $$\text{conv} \{ e_1,e_2,e_3, (1/2, 1/2, 1) , (1/2, 1, 1/2) , (1, 1/2, 1/2) \}$$
can be reduced to a convex hull of a subset of these vectors?
That is, if $D = \{ e_1,e_2,e_3, (1/2, 1/2, 1) , (1/2, 1, 1/2) , (1, 1/2, 1/2) \}$ does there exist a proper subset $S \subset D$ such that $\text{conv}(D) = \text{conv}(S)$ ?
By inspection it seems that I cannot write any of the vectors as a convex combination of the others, does this imply that $D$ is minimal ?
If a finite set of points satisfies a linear inequality, so does any convex combination of those points. Hence, given a finite set $S$ and a point $t$, if there is a linear inequality that is satisfied by $t$ but not by any member of $S$ then $t\notin \operatorname{conv}(S)$.
Let us now look at every point of $D$.
Point $e_1=(1,0,0)$ satisfies the linear inequality
$$-x+y+z\le -1$$
but none of the other points of $D$ do. [$e_2, e_3,(\frac 12,\frac 12,1),$ and $(\frac 12,1,\frac 12)$ make the left hand side yield $1$, and $(1,\frac 12,\frac 12)$ yields $0$]. Thus $e_1$ cannot be in the convex hull of any subset of $D$ that does not include $e_1$, and therefore $e_1$ must be in any subset $S$ of $D$ that has the same convex hull.
Point $e_2=(0,1,0)$ is the only point in $D$ that satisfies $x-y+z\le -1$.
Point $e_3=(0,0,1)$ is the only point in $D$ that satisfies $x+y-z\le -1$.
Point $(\frac 12,\frac 12,1)$ is the only point in $D$ that satisfies $x+y+2z\ge 3$.
Point $(\frac 12,1, \frac 12)$ is the only point in $D$ that satisfies $x+2y+z\ge 3$.
Point $(1,\frac 12,\frac 12)$ is the only point in $D$ that satisfies $2x+y+z\ge 3$.
We conclude that every point in $D$ must be in any subset of $D$ that has the same convex hull. Therefore, $D$ is minimal.