My question is can the following exist as a simple graph? Or is it not possible?
The graph is to have 7 vertices and 7 edges and is connected. Also, if any one of its edges is removed, it will not disconnect the graph.
My thought is that it does not exist (purely based on 'try and error'), but I am having trouble explaining the reason in words.
Appreciate the help!
As $\sum\limits_{v\in V}\deg(v) = 2|E|$ by the handshaking lemma, we get that the average degree of each vertex must be $2$.
As the removal of any edge will not disconnect the graph we get that $\delta(G)> 1$ as otherwise a degree $1$ vertex could be disconnected from the graph by removing it's sole edge.
These two facts together imply that the graph must in fact be $2$-regular. The only $2$-regular connected graphs possible are the cycle-graphs.
We learn then that the only graph possible which matches your stated conditions (connected, 7 vertices, 7 edges, and edge-connectivity at least $2$) is going to be the graph $C_7$.
(image from wolfram mathworld)