Every definition of $\mathbb{C}$ that I can think of uses $\mathbb{R}$. We can let $\mathbb{C}=\mathbb{R}^2$ equipped with a particular multiplication. We can let $\mathbb{C}$ be the algebraic closure of $\mathbb{R}$.
The best way I could come up with to define $\mathbb{C}$ without $\mathbb{R}$ is to let $\mathbb{C}$ be the "completion" of the algebraic closure of the rational numbers. I'm not really sure what the "completion" would mean in this case. Can anyone finish this idea, or suggest a different approach?
If all you want is to define $\mathbb C$, you could do it along this path:
I haven't done the details, but I suppose we can show reasonably painlessly that $\mathbb C$ is a field extension of $\mathbb Q[i]$.
On the other hand it could be a real challenge to prove the fundamental theorem of algebra -- that is, that our $\mathbb C$ is algebraically closed -- without introducing $\mathbb R$ and its topology through a back door somewhere along the way. Withough $\mathbb R$ there would be no intermediate value theorem, for example.