The problem statement:
Suppose $f:\mathbb{R} \to \mathbb{R}$ is continuously differentiable, $f'(x)$ is strictly increasing, with $\lim_{x \to -\infty}f'(x) = -\infty$, $\lim_{x \to \infty}f'(x) = \infty$, $f(0) \neq 0$.
a) Prove that $\forall \xi \neq 0$, there exists an $\eta$ such that $f(\xi + \eta) = f(\xi) + f(\eta)$
b) Prove that through this point $(\xi, \eta)$ there is a solution $y=\phi(x)$ of $f(x+y) = f(x) + f(y)$ which is unique in a neighborhood of $(\xi, \eta)$.
c) Construct an example to show that when $\xi = 0$ there may be no corresponding $\eta$.
a) Define $h(x) = f(x+\xi) - f(x) - f(\xi)$. Applying the mean value theorem to $f(x+\xi)-f(x) = \xi f'(\gamma)$, where $\gamma \in (x, x+\xi)$. If we take the limit as $x \to \pm \infty$, we must have that $\gamma$ tends to $\pm \infty$ as well. This implies $\lim_{x \to -\infty} h(x) = -\infty$ and $\lim_{x \to \infty} h(x) = \infty$. Since $h$ is continuous by construction, the intermediate value theorem gives $h(\eta) = 0$ for some $\eta$.
b) Let $g(x,y) = f(x+y) - f(x) - f(y)$. By a), we know that $\exists (\xi, \eta)$ s.t. $g(\xi, \eta) = 0$. Further we note that the partial derivatives of $g$ are sign definite, since $$g_x = f'(x+y) - f(x) \quad g_y = f'(x+y) - f'(y)$$ and we can conclude these are nonzero by the fact that $f'$ is one-to-one on all of $\mathbb{R}$ (continuous monotone function is one-to-one). Then by the implicit function theorem, there exists a solution $y=\phi(x)$ to the functional equation that is unique in a neighborhood of $(\xi, \eta)$.
c) Consider $f(x) = x^2 + 1$. $f'(x)$ satisfies the requirement, but $$x^2+1=f(x) = f(x + 0) \neq f(x) + f(0) = x^2+2$$ Clearly we cannot apply the implicit function theorem because we do not have the condition in a). We can also deduce that we must have $f(0) = 0$ which is a contradiction to the problem statement.
Many thanks to Pp.. for nursing me through this one!