Taken from here consider the $n$-simpliex $\Delta^n\subseteq\mathbb{R}^{n+1}$ defined by $$ \textstyle \Delta^n = \{x=(x_0,\dots,x_n)\in\Bbb R^{n+1}\mid \sum_0^n x_i=1,\,x_i\ge0\,\forall i \}, $$ whose interior, as discussed in this post, is given by $$ \textstyle \text{int}(\Delta^n) = \{x=(x_0,\dots,x_n)\in\Bbb R^{n+1}\mid \sum_0^n x_i=1,\,x_i>0\,\forall i \}. $$
It seems like this is a 1-chart smooth manifold (and $\Delta^n$ is a 1-chart manifold with boundary), but what exactly would be a smooth map $f:\mathbb{R}^n \rightarrow \text{int}(\Delta^n)$?
One mapping that works is as follows: interpret $\mathbb R^n$ as the subset of $\mathbb R^{n+1}$ of vectors whose final coordinate is 0. Then we can define $f: \mathbb R^n \to \mathrm{int}(\Delta^n)$ as $$ f(v)_i = \frac{\exp(v_i)}{\sum_{i = 0}^n \exp(v_i)}. $$