Let $A = \{ A_k | k \in K \}$ be a family of sets indexed by $K$. By Zermelo's theorem, $K$ can be well-ordered. Now, let $\leq$ be a well-order on $K$.
Define
$j: \bigcup\limits_{k \in K} A_k \to K$,
$j(x)=\min_{\le}\{k\in K:x\in A_k\}$
Is this function injective? How can this be checked and proved or disproved?
Let $A_1 = \{1,2\}, A_2 = \{2,3\}$. Then $K = \{1,2,3\}$.
Then, $j(1) = 1$, $j(2) = 1$, so this is not injective.
Question for you: What if each $A_i$ contains at most 1 element? Then what can you say?