We can use $h^n(X)=\langle X,K(G,n)\rangle $ to define a reduced cohomology theory. I wonder if we can use the basepoint-preserving homotopy classes $\langle -,-\rangle $ to define homology?
And I wonder if the cohomology and homology functors are adjoint?
The answer to both questions is no.
For the first question, if $H_n$ were representable it would preserve products in the homotopy category, which are just the usual products : but it doesn't, so it's not representable.
For the second one : neither $H^n$ nor $H_n$ preserves products (see the Künneth formula), which are also products in the homotopy category, so neither of them is a right adjoint.