Does there exist EXACT zeros of Error Function (Erfc(z)) and Parabolic Cylinder Function ($D_v(z)$)(http://functions.wolfram.com/HypergeometricFunctions/ParabolicCylinderD/). Here (https://dlmf.nist.gov/12) (section 12.2 and 12.11) is the discussion about the real zeros of $D_v(z)$ but I don't understand about the complex zeros. I am particularly interested for the exact complex zeros of $D_{-\frac{1}{2}}(z)$ and $D_{-\frac{1}{2}}(iz)$.
I think I would be able to proceed on my work, if equivalently, I know if there exists a zero (except $z=0$) of error function.
Both erfc and $D_{-1/2}$ have infinitely many complex zeros. I doubt very much that you'll get closed forms for them. The closest zeros to $0$ for $\text{erfc}$ are approximately $-1.354810128 \pm 1.991466843 i$. The closest zeros to $0$ for $\text{D}_{-1/2}$ are approximately $-2.110851502 \pm 2.267049242 i$.
Here are the zeros of erfc (red) and $D_{-1/2}$ (blue) for $-10 < \text{Re}(z), \text{Im}(z) < 10$.