I got part a, since the rows must sum to 1 $a = 2$ and $b = 6$. I am confused on b,c, and d. I would love some hints on how to approach these parts of the problem.
For b, I was thinking that $P(X_{4.7} = 1$ and $ X_1 = 1 | X_{1.3}=2$ and $X_0 =0) = P(X_{4.7} = 1, X_1 = 1 | X_{1.3}=2)$ by the Markov Property. Then I am stuck here and how to re-write the probability so that I can use the transition probabilities in the matrix.
For c, I was thinking that $P(X_6 =1) = P(X_6 = 1 | X_t = 2)$ for $t \in [0,6)$. Using $Q= P'(0)$, we need $q_{22}$ and $q_{21}$. So, $q_{21}$ at $t = 0$ is 2 and $q_{22}$ at $t = 0$ is -3 so $T(2,1) = \frac{q_{21}}{-q_{22}} = \frac{2}{3}$. I am not sure if this is a correct way of thinking about this problem or even accurate.
And lastly, for d, I am thinking to find Q and solve $\pi * Q = 0$ and $\pi_0 + \pi_1 + \pi_2 = 1$, but again, I am not sure if this is what the question is asking. I would appreciate any and all help. Thank you!

Hints
You're on the right track to make use of the Markov property, but your equation isn't correct as it stands, because the time index for one of the conditioning events (viz. $\ X_{1.3}=2\ $) is greater than one of those in the conjunction whose conditional probability is being calculated (viz. $\ X_1=1\ $). It might be possible for someone very familiar with Markov chains to write down the correct equation without any calculation, but the only way I can do it is to expand out various conditional probabilities using their definitions: \begin{align} \hspace{1.5em}\mathbb{P}\big(X_{4.7}=1,&\,X_1=1\,\big|\,X_{1.3}=2,X_0=0\big)\\ &=\frac{\mathbb{P}\big(X_{4.7}=1,X_1=1,X_{1.3}=2,X_0=0\big)}{\mathbb{P}\big(X_{1.3}=2,X_0=0\big)}\\ &=\frac{\mathbb{P}\big(X_{4.7}=1,X_1=1,X_{1.3}=2,X_0=0\big)}{\mathbb{P}\big(X_1=1,X_{1.3}=2,X_0=0\big)}\\ &\hspace{1em}\times \frac{\mathbb{P}\big(X_1=1,X_{1.3}=2,X_0=0\big)}{\mathbb{P}\big(X_1=1,X_0=0\big)}\\ &\hspace{1em}\times\frac{\mathbb{P}\big(X_1=1,X_0=0\big)}{\mathbb{P}\big(X_0=0\big)}\\ &\hspace{1em}\times\frac{\mathbb{P}\big(X_0=0\big)}{\mathbb{P}\big(X_{1.3}=2,X_0=0\big)}\\ &=\mathbb{P}\big(X_{4.7}=1\,\big|\,X_1=1,X_{1.3}=2,X_0=0\big)\\ &\hspace{1em}\times \mathbb{P}\big(X_{1.3}=2\,\big|\,X_1=1,X_0=0\big)\\ &\hspace{1em}\times\frac{\mathbb{P}\big(X_1=1\,\big| \,X_0=0\big)}{\mathbb{P}\big(X_{1,3}=2\,\big|\,X_0=0\big)}\\ &=\mathbb{P}\big(X_{4.7}=1\,\big|\,X_{1.3}=2\big)\mathbb{P}\big(X_{1.3}=2\,\big|\,X_1=1\big)\\ &\hspace{1em}\times\frac{\mathbb{P}\big(X_1=1\,\big| \,X_0=0\big)}{\mathbb{P}\big(X_{1.3}=2\,\big|\,X_0=0\big)}\ , \end{align} where it is only in the last equation that all the conditional probabilities have the right form for the Markov property to be applicable.
The definition of the transition matrix $\ \mathbf{P}\ $ is $$ \mathbf{P}_{ij}(t)=\mathbb{P}\big(X_{s+t}=j\,|\,X_s=i\,\big)\ , $$ for all $\ s\ $ and $\ t>0\ $, independent of $\ s\ $, which means that the Markov chain is time-homogeneous: \begin{align} \mathbb{P}\big(X_b=j\,\big|\,X_a=i\big)&=\mathbb{P}\big(X_{(b-a)+a}=j\,\big|\,X_a=i\big)\\ &=\mathbf{P}_{ij}(b-a)\ . \end{align} You should be able to use this identity to calculate all the probabilities needed to answer part (b).
For (c), by the Markov property, for any $\ s\in[0,6)\ $we have \begin{align} \mathbb{P}\big(X_6=1\,\big|&\,X_t=2\ \text{ for all }\ t\in[0,6)\big)\\ &=\mathbb{P}\big(X_6=1\,\big|\,X_t=2\ \text{ for all }\ t\in[s,6)\big)\\ &=\frac{\mathbb{P}\big(X_6=1\ \text{ and }\ X_t=2\ \text{ for all }\ t\in[s,6)\big)}{\mathbb{P}\big(X_t=2\ \text{ for all }\ t\in[s,6)\big)}\\ &\le\frac{\mathbb{P}\big(X_6=1, X_s=2\big)}{\mathbb{P}\big(X_s=2\big)e^{q_{22}(6-s)}}\\ &=\frac{\mathbb{P}\big(X_6=1\,\big|\,X_s=2\big)}{e^{q_{22}(6-s)}}\\ &=\frac{\mathbf{P}_{21}(6-s)}{e^{q_{22}(6-s)}} \end{align} Since this final expression tends to $\ 0\ $ as $\ s\uparrow6\ $, what does that tell you about the value of $\ \mathbb{P}\big(X_6=1\,\big|\,X_t=2\ \text{ for all }\ t\in[0,6)\big)\ $?
You're given all the entries of $\ \mathbf{P}(t)\ $ explicitly as functions of $\ t\ $, so you should be able to determine whether $\ \lim_\limits{t\rightarrow\infty}\mathbf{P}(t)\ $ exists, and what its value is if it does, simply by doing this for each of the entries of $\ \mathbf{P}(t)\ $ .