To define $\mathbb{R}$, one approach is to start with $\mathbb{N}$ and then systematically introduce $\mathbb{Z},$ $\mathbb{Q}$, and then $\mathbb{R}$. Alternatively, we define $\mathbb{R}$ using its axiomatic definition that it is a complete ordered field. And then, we can construct $\mathbb{N}$, $\mathbb{Z}$ and $\mathbb{Q}$ within $\mathbb{R}$.
Now, $\mathbb{C}$ is introduced in the first way, by making $\mathbb{R}^2$ as a field. Can we follow the latter approach of defining $\mathbb{C}$ axiomatically, and then construct $\mathbb{R}$ inside it?
Perhaps the unique algebraically and topologically complete partially ordered field of characteristic $0$?However, I am not sure it is true - dropping from ordered to partially ordered opens up a lot of freedom that may allow other contenders.
I am modifying this answer (the idea above is highly doubtful) to address Arvind's questions in the July 6 comment below.
Here is an outline of one approach to prove that $\Bbb C$ is, up to isomorphism, the only connected, locally compact topological field of characteristic $0$ which remains connected when $0$ is removed. There may be easier approaches, and I have not gone through the steps myself to make sure there are no significant hurdles that I am overlooking, but this is the approach I would try:
Let $\mathscr C$ be a connected, locally compact topological field of characteristic $0$ for which $\mathscr C \setminus \{0\}$ is also connected. We need to show that $\scr C$ is isomorphic to $\Bbb C$ as topological fields.