From wikipedia I obtain the following definition of an injective function :
Let $f$ be a function whose domain is a set $A$. The function $f$ is injective if for all $a$ and $b$ in $A$, if $f(a) = f(b)$, then $a = b$; that is, $f(a) = f(b)$ implies $a = b$.
From this I conclude that a function $f$ is injective if the below statement is true for all $a,b \in A$:
$$f(a)=f(b) \implies a=b$$
My question is: Can I re-formulate the above statement as $f(a)=f(b) \iff a=b$ ?
Yes, but the implication $a=b\Rightarrow f(a)=f(b)$ holds because you have a function. So in a sense it is redundant.
That is, "$f$ is a function" implies "$a=b\Rightarrow f(a)=f(b)$". So $$\begin{align*} f\text{ is an injective function} &\text{is equivalent to } f\text{ is a function and f is injective}\\ &\text{is equivalent to } f\text{ is a function and } f(a)=f(b)\Rightarrow a=b\\ &\text{implies }\Bigl( (a=b\Rightarrow f(a)=f(b))\text{ and }(f(a)=f(b)\Rightarrow a=b)\Bigr)\\ &\text{is equivalent to } f(a)=f(b)\Leftrightarrow a=b. \end{align*}$$ Conversely, since "$f$ is a function and $a=b \Rightarrow f(a)=f(b)$" is equivalent to "$f$ is a function", you also have the implication going the other way provided you know that $f$ is a function.