Let $X$ be any set containing at least three distinct elements $a,b,c\in X$. Let $S$ be the relation on $\mathbb{P}(X)$ such that $(A,B)\in S$ when $A\cap B=\{a\}$.
I'm not even sure how to write out this relation.
Here's a start: $S = \left\{(a,b)\in \mathbb{P}(X) \times \mathbb{P}(X)\mid A\cap B=\{a\}\right\}$.
Unfortunately that doesn't make any sense to me.
That's almost right, except it should say $(A,B)$ instead of $(a,b)$.