I'm having a very hard time to separate estimates on population values versus estimates on sample values.
I'm struggling with this exercise (not homework, self-study for my exam in introductionary statistic course):

a) Calculate the maximum likelihood estimate on $\lambda$ and name this $\hat{\lambda}$
I did this. First I calculated the maximum likelihood estimator for $\lambda$, which is $\hat{\lambda}=\frac1n \sum_{i=0}^n k_i$
And the maximum likelihood estimate was $\hat{\lambda_e}=\frac{15}6=2.5$
Hopefully this is right. But now I'm asked to calculate the "estimates on $E(X)$ and $E(Y)$ and afterwards I'm asked to calculate the estimate on both the variance and standarddeviation on the estimate, $\hat{\lambda}$?
I'm really struggling to separate the two from each other, so any hint or guidance would be much appreciated.
It's not clear how you got $15/6$. The sample mean is \begin{align} & \frac{\overbrace{0+\cdots+0}^{\text{123 of these}}+\overbrace{1+\cdots+1}^{\text{67 of these}}+ \overbrace{2+\cdots+2}^{27}+\overbrace{3+\cdots+3}^{10}+5}{123+67+27+10+0+1} \\[10pt] = {} & \frac{156}{228} = 0.68421\ldots \end{align} For the Poisson distribution the variance is the same as the mean, and you can take the statistic above to be an estimate of the mean and of the variance.
The variance of $\hat\lambda$ is \begin{align} & \operatorname{var}\left(\frac{X_1+\cdots+X_{228}}{228}\right) = \frac 1 {228^2}\operatorname{var}(X_1+\cdots+X_{228}) \\[10pt] = {} & \frac 1 {228^2} \left(\operatorname{var}(X_1)+\cdots+\operatorname{var}(X_n) \right) =\frac 1 {228^2} (\lambda+\cdots+\lambda) \\[10pt] = {} & \frac 1 {228^2} \cdot 228\lambda = \frac \lambda {228}. \end{align}