For a smooth curve $\alpha:I\to \mathbb{R}^3$ with $[a,b]\subset I$,
if $$|\alpha(b)-\alpha(a)| = \int_a^b |\alpha'(t)|dt$$ holds
Does the curve with the equation hold a line segment?
We can show for any smooth curve with point $\alpha(a),\alpha(b)$ fixed we have $|\alpha(b)-\alpha(a)| \le \int_a^b |\alpha'(t)|dt$ ,line segment between these two points are the one with lower bounded is attained.
If you have equality in the following inequality
$$ |\alpha(b) - \alpha(a)| = \left|\int_a^b \alpha '(t)dt\right| \leq \int_a^b |\alpha '(t)| dt $$
then since $\alpha$ is smooth there exists $\theta$ such that for all $t \in [a,b]$,
$$ \alpha'(t) = e^{i\theta}|\alpha'(t)| $$
(see the case of equality in the complex integral triangle inequality).
Therefore
$$ \alpha(b) - \alpha(a) = \int_a^b \alpha'(t)dt = e^{i\theta}\int_a^b |\alpha'(t)|dt $$
and for all $t \in [0,1]$
$$ \begin{aligned} \alpha(a + t(b-a)) &= \alpha(a) + \int_a^{a + t(b-a)} \alpha'(t)dt \\ &= \alpha(a) + e^{i\theta}\int_a^{a + t(b-a)} |\alpha'(t)|dt \\ &= \alpha(a) + \underbrace{\frac{\int_a^{a + t(b-a)} |\alpha'|}{\int_a^b |\alpha'|}}_{= \phi(t) \in [0,1]} (\alpha(b) - \alpha(a)) \end{aligned} $$
so $\alpha([a,b])$ is indeed the segment $ [\alpha(a),\alpha(b)] $ because $\phi : [0,1] \rightarrow [0,1]$ is continuous, non-decreasing and $\phi(0) = 0$, $\phi(1) = 1$.
Does that help you?