How does one calculate the eigenvalues of a unitary 3 by 3 block circulant matrix where
$$U = -\frac{i}{3} \begin{pmatrix} \Lambda_{1} & \Lambda_{2} & \Lambda_{3} \\ \Lambda_{3} & \Lambda_{1} & \Lambda_{2} \\ \Lambda_{2} & \Lambda_{3} & \Lambda_{1} \end{pmatrix}$$
where
$$ \Lambda_{1} = \begin{pmatrix} 0 & 1 & 0 & 0 \\ 1 & 0 & 0 & -2\sqrt{2} \\ -2\sqrt{2} & 0 & 0 & -1 \\ 0 & 0 & -1 & 0 \end{pmatrix}, \quad \Lambda_{2} = \begin{pmatrix} 0 & 0 & -2\sqrt{2} & 0 \\ 0 & 0 & 0 & 0 \\ 0 & 0 & 0 & 0 \\ 0 & 0 & 0 & 0 \end{pmatrix} , \quad \Lambda_{3} = \begin{pmatrix} 0 & 0 & 0 & 0 \\ 0 & 0 & 0 & 0 \\ 0 & 0 & 0 & 0 \\ 0 & -2\sqrt{2} & 0 & 0 \end{pmatrix} $$
This won't be a full answer, but here's some thoughts that (I think) should move you in the right direction.
Let $P$ denote the matrix $$ P = \pmatrix{0&1&0\\0&0&1\\1&0&0} $$ Then, in terms of Kronecker products, we can write your matrix as $$ 3iU = I \otimes \Lambda_1 + P \otimes \Lambda_2 + P^2 \otimes \Lambda_3 $$ It is actually very easy to calculate the eigenvalues of $(P \otimes \Lambda_2 + P^2 \otimes \Lambda_3)$: notably, $\Lambda_2,\Lambda_3$ commute, and are both nilpotent. It follows that $P \otimes \Lambda_2$ and $P^2 \otimes \Lambda_3$ are also commuting nilpotent matrices. It follows that $(P \otimes \Lambda_2 + P^2 \otimes \Lambda_3)$ is a nilpotent matrix, which means that its only eigenvalue is $0$. Moreover, it satisfies $(P \otimes \Lambda_2 + P^2 \otimes \Lambda_3)^2 = 0$. Its rank is at most $3$.
The $\Lambda_1$ term, however, makes things a bit tricky, and I'm not sure how to continue this line of analysis.
Here's a "brute force" approach that might help.
I hope you find these observations to be useful.