Elusive common geometric parameter / property in spherical triangles set

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A constant length $(=a)$ segment of a variable great circle has its extremities $(P,Q)$ moving along fixed Longitudes $(L1,L2)$ passing through North pole $N.$

Please help to identify the geometric parameter with invariant property $\dfrac{\sin a}{\sin A}$ associated with the set of spherical triangles $ NPQ.$

Elusive common Invariant