I am trying to compare these two collections. Specifically, I am interested in examining $\Pr(Y_u - X_u > z)$ where $X_u$ and $Y_u$ denote the sample means of each. We can assume $X_i$ and $Y_i$ are all independent of each other
Here is what I was working on:
If we have both $X, Y \sim \operatorname{Exp}(\lambda)$ then we can make the joint distribution: $\frac{1}{\lambda^2} e^{-\frac{x}{\lambda}}e^{-\frac{y}{\lambda}}$. Let's say $Z = X - Y$.
From here we say
\begin{align} F_Z(z) &= 1 - P(Z > z) \\&= P(Y \geq z) \\& = 1 - \int_z^\infty \int_0^{x-z}\frac{1}{\lambda^2} e^{-\frac{x}{\lambda}}e^{-\frac{y}{\lambda}} \,dy\, dx \\& = 1 - \frac{1}{2}e^{-\frac{z}{\lambda}} \end{align}
If I plug in some values though this doesn't seem to represent what I had initially set out to find. Let me know if I need to add more details.
EDIT: If the sample size is large enough can this be approximated through some application of CLT?

The sample mean of $X_1, \ldots, X_n$, which you denote $X_u$, is gamma distributed, namely $$X_u \sim \operatorname{Gamma}(n, n\lambda), \\ f_{X_u}(x) = \frac{(n \lambda)^n x^{n-1} e^{-\lambda x/n}}{\Gamma(n)}, \quad x > 0.$$ Similarly, $$Y_u \sim \operatorname{Gamma}(n, n\lambda).$$ Their difference, $Z = Y_u - X_u$, is known as a variance-gamma distribution which does not have an elementary closed form for either the density or survival; the density, however, is expressible in terms of Bessel functions. Specifically, $$Z \sim \operatorname{VarianceGamma}(\mu = 0, \lambda^* = n, \alpha = n\lambda, \beta = 0),$$ where $\mu$ is the location parameter, $\lambda^*$ is a shape parameter (not to be confused with $\lambda$, but corresponds to $\lambda$ in the Wikipedia article I linked to), $\alpha$ is another shape parameter, and $\beta$ is a skewness parameter. For $n$ sufficiently large, the shape of this density begins to approximate a normal distribution with mean $0$ and variance $2/(n \lambda^2)$.