Let us consider a biased random walk in $\mathbf{Z}$ whose step-lengths satisfy $\mathbf{P}(\xi = +1) = p > \mathbf{P}(\xi = -1) = q$ (with $p+q = 1$).
A value $k \in \mathbf{Z}$ is a "separator" of the random walk if the random walk started before $k$ passes through $k$ only once.
By the strong Markov property $\mathbf{P}_k(0 \text{ is separator}) = \mathbf{P}_0(\text{The random walk never returns to zero}).$ Denote by $A_k$ the probability of the random walk, started at $k \neq 0,$ to never visit zero and $A_0$ be the probability of never return to zero. By the strong law of large numbers, $A_k = 0$ for all $k$ negative. Now, using first step analysis is easy to deduce $A_{k + 1} = q A_k + pA_{k + 2}$ for $k \geq 1,$ $A_0 = p A_1$ and $A_1 = p A_2.$ Then, we have $$A_{k + 2} - A_{k + 1} = \dfrac{q}{p}(A_{k + 1} - A_k) \quad (k \geq 1).$$ It is easy to show $A_{k+2}-A_{k+1}=(\frac{q}{p})^{k+1} A_1$ which then leads to, by means of a telescopic sum, $$A_k=\dfrac{1}{p} \left[ \sum_{j=0}^k \left( \dfrac{q}{p} \right)^j \right] A_0.$$ This shows that $A_k \to \dfrac{1}{p} \dfrac{1}{1 - \frac{q}{p}} A_0 = \dfrac{1}{p-q}A_0.$
My intuition suggests strongly that $A_k \to 1.$ How to prove this formally?
Having this, I can conclude $A_0 = p - q,$ which is very reasonable. So, the probability of zero being separator, starting at $k < 0$ is simply $p - q.$
Consider now the set $\mathrm{X}_a = \{a\text{ is a separator}\}.$ The previous can be restated as $$\mathbf{P}_0(\mathrm{X}_a) = p - q$$ for every $a \geq 0.$
Can I use the previous formula to conclude $\mathbf{P}_0\left(\bigcup\limits_{a = 0}^N \mathrm{X}_a\right) \to 1$ as $N \to \infty$?
You can show that $$ (1-A_k)=(1-A_1)^k\qquad\text{for all $k\ge 1$}\tag{$*$} $$ Why? You know $1-A_k$ is the probability of starting from $k$ and eventually hitting $0$. This is equal to the probability of starting from $k$ and moving eventually to $k-1$, then starting from $k-1$ and moving eventually to $k-2$, then $\dots$ then starting from $1$ and moving to $0$. But moving from $i$ to $i-1$ is the same as moving from $1$ to $0$, so each event in that list of $k$ events has probability $(1-A_1)$.
Plugging $(*)$ with $k=2$ and $k=3$ into $$ A_2=pA_3+qA_1, $$ you can solve for $A_1$. You will find that $A_1<1$, so that $(*)$ implies $A_k\to 1$ as $k\to\infty$ .