Let $K\subset\mathbb{R}^d$ be compact such that $K^\circ\neq\emptyset$. Let $U\subset\mathbb{R}^d$ bounded and open ($U$ could e.g. be chosen to be the open unit ball). Let $Φ: K^\circ\to U$ be a diffeomorphism.
Can I find a set $V \supset K$ open and a diffeomorphism $\Psi: V \to \Psi(V)$ such that $\Psi|_{K^\circ} = \Phi$? The range of $\Psi$ is of no great importance to me, I only care that it's a proper superset of $U$.
A similar question was asked at Extending a diffeomorphism outside a compact set where a counterexample was given for non-contractable sets. However, the question asked for an extension onto the whole space $\mathbb{R}^d$, whereas I'm only interested to extend $\Phi$ a little bit outside of $K$.
The answer is, in full generality, no. I will use Riemann's uniformisation Theorem:
Consider $\Delta = \left\{ z \in \mathbb{C} \mid |z|<1 \right\}$ and $U$ the interior of a Von Koch curve. Then $\Delta$ and $U$ are non-empty simply connected open subsets of $\mathbb{C}$: there exists a diffeomorphism $\varphi\colon \Delta \to U$.
Suppose by contradiction that $\varphi$ extends to $\psi \colon V \to \psi(V)$ as a diffeomorphism with $\overline\Delta \subset V$. Then $\psi(\partial\Delta) = \partial \psi(\Delta) = \partial U$ and $\psi$ maps the unit circle to the Von Koch curve. But a diffeomorphism sends smooth curves to smooth curves, which is a contradiction. It follows that $\psi$ does not exist.
Comment: there is no reason for a smooth / conformal / holomorphic map to extend to the boundary of a domain, as shows the above example. We indeed could have chosen a square, heptagone or any non-smooth curve instead of the Von Koch curve, but this example shows how pathological it can be (and in fact, it can be even worse).