I want to know whether it is possible that a point be an extremum without the derivative at that point being zero ?
I encountered this point when reading about the fact that entropy maximizes as function of energy but we know that $1/T=\frac{\partial S}{\partial E}$ (assuming Entropy is smooth and differentiable in the desired domain) which would make temperature infinite.
I already read a similar post on Physics Stackexchange but didn't get satisfactory answer.
It is possible, if your domain is compact with boundary or has a discontinuity: for the easiest example, think of a graph of a straight line y=x on $0 \leq x \leq 10$ having a maximum at (10, 10) and a minimum at (0,0).
If there's a discontinuity in the domain or the range (far more treacherous), an extremum could occur there (again, the graph of the function would 'break off' and continue elsewhere).