I've managed to work out that the length $AB$ is $\sqrt{3} r$
I'm getting completely different answers from the correct one for part b of the question: $\sqrt{3}\pi r$
I'm not even $100%$ sure if it is referring to the circumference of the major or minor segment. I've tried to work out both and still don't get that answer. Any tips?
Cheers!!

I think you are misunderstanding the wording of the problem. Once you find the length AB you can very easily use the formula $\pi\times \mbox{diameter}$ to find the circumference the question refers to. The diameter is the length AB; simply multiply it by $\pi$ to answer part b.