I have no reason to expect this to be true, but I thought it wouldn't hurt to ask.
For a Galois number field $K/\mathbb{Q}$, and a rational prime $(p)$ with a prime $\mathfrak{q}_i\subseteq\mathcal{O}_K$ lying above it, the decomposition group is defined as: $$ D = D_{\mathfrak{q}_i\mid p} = \{\sigma\in\text{Gal}(K/\mathbb{Q})\mid \sigma(\mathfrak{q}_i) = \mathfrak{q}_i\} $$ This is just the stabilizer of the action of $\text{Gal}(K/\mathbb{Q})$ on the prime ideals lying above $p$.
Is there anything known about, given a particular group $D$, which pairs of $(K,p)$ have this group as a decomposition group?
I'm interested in the case of $D = \mathbb{Z}/2\mathbb{Z}$ specifically, which may be simple enough that something about it is known.
Let's think about the case when $K=\mathbb{Q}(\sqrt{d})$ is a quadratic field to start with.
To get a non-trivial decomposition group above a rational prime $p$, you need the prime to split or ramify. In other words, applying the Kummer-Dedekind theorem, we want the polynomial $x^2-d$ to be reducible $\bmod{p}$; i.e. $d$ should be a square $\bmod{p}$. Indeed if $\alpha,\beta$ are roots, then your two primes above $p$ are $(\alpha,p)$ and $(\beta,p)$ which are permuted by Galois.
(Note to apply Kummer-Dedekind, I should suppose generally that $p \nmid 4d$ or work properly with the minimal polynomial of a generator for the ring of integers of $K$).
In the general case, note that since the decomposition group is a subgroup, its order must divide the degree $[K:\mathbb{Q}]$. With that done, Chebotarev's density theorem then says that this will happen infinitely often for primes (indeed each element has an equal chance so just count the number of order 2 elements in your Galois group). You are however unlikely to get a full description like the quadratic case.