I'm trying to find the standard deviation of $Z = X + Y$ given the following table:
I'm getting $E[Z^2] = 36.31$ and $E[Z] = 5.45$, giving me a variance of
$Var[X] = 36.31 - (5.45)^2 = 6.6075$ and a standard deviation of $\sqrt{6.6075} = 2.57$.
I'm off by a bit on this question. Any help would be appreciated.

I think you need to check your calculations. For example, I get $E(Z) =6.15$, but I haven't checked $E(Z^2)$ yet. Would it be cheating to chuck this into an excel spreadsheet?