With the exception of $d = 5$, which gives $\mathbb{Z}[\phi]$, of course (as was explained to me in another question). I'm not concerned about $d$ negative here, though that might provide a clue I have overlooked.
What I thought about was the fact that $2, 3, 7$ are irreducible in such a domain. But that does not necessarily guarantee that at least one of $6, 14, 21$ is going to have an alternate distinct factorization. I also have this vague inkling that $5$ being prime has something to do with it.
EDIT: Oops, sorry, I forgot to specify $d$ is squarefree. Thank you for forgiving this little mistake.
The following proof uses ideas due to Ennola (Two elementary proofs concerning simple quadratic fields) and Redei (Über die quadratischen Zahlkörper mit Primzerlegung) and can be used to show that a necessary condition for ${\mathbb Q}(\sqrt{m})$ to have unique factorization is that its discriminant is prime or a product of two negative prime discriminants.
Assume that $K = {\mathbb Q}(\sqrt{5m})$ has unique factorization and consider the ideal $P = (5,\sqrt{m})$. Then $P^2 = (5)$. Since $K$ has unique factorization, $P$ is principal, hence there exists $\pi \in {\mathcal O}_K$ with $P = (\pi)$. From $P^2 = (\pi^2) = (5)$ we deduce that there exists a unit $\eta \in {\mathcal O}_K$ with $\pi^2 = 5\eta$.
If $m < 0$, then $\eta = \pm 1$, hence $\sqrt{5} \in K$ or $\sqrt{-5} \in K$: contradiction.
If $m > 0$, then either $\eta = 1$ and $m = 1$, i.e., $K = {\mathbb Q}(\sqrt{5})$, or $\eta \ne 1$. In the second case we have $m > 1$, and we may assume that $\eta$ is the fundamental unit (squares of units may be subsumed into $\pi$). Then there is a prime $q \mid m$, and as above we find that $q\eta = \lambda^2$. This implies $\sqrt{5q} \in K$, hence $K$ is the product of two prime discriminants. In addition, $25N(\eta) = N(5\eta) = N(\pi^2) = 25$ implies that $N\eta = +1$, so the fundamental unit has norm $+1$.
Since $q \equiv 1 \bmod 4$ (discriminants are never $\equiv 3 \bmod 4$) we can write $5q = a^2 + b^2$ with $a$ odd. Setting $\alpha = b + \sqrt{5q}$ and $Q = (a,\alpha)$ we find from $\alpha \alpha' = -a^2$ that $Q^2 = (a^2,2a\alpha,\alpha^2) = (\alpha\alpha',2a\alpha,\alpha^2) = (\alpha)(\alpha',2a, \alpha) = (\alpha)$ since $\alpha$ and $\alpha'$ are coprime as ideals. Since $Q = (\omega)$ is principal, the element $\omega^2/\alpha$ is a unit with negative norm: contradiction.
In the proof we have used that unique factorization holds if and only if $h = 1$. If $P = (5,\sqrt{5m})$ is not principal, then $5 \cdot m = \sqrt{5m} \cdot \sqrt{5m}$ is an example of non-unique factorization. If $P$ is principal (e.g. when $m = 41$), then $-a^2 = (b+\sqrt{5m})(b-\sqrt{5m})$ should give rise to an example of non-unique fasctorization, but I haven't checked the details.