I am given that $$a \equiv 11 \pmod {19}$$ and $$ c \equiv 13a \pmod {19}$$ and I am asked to solve for a $c$ that is between $0$ and $18$ inclusive.
From looking at problems online, it seems that the easiest way to do this is as follows:
$$ c \equiv 13(11) \pmod {19}$$ $$ c \equiv 143 \pmod {19}$$ $$ 143 = 19(7) + 10$$ therefore $$ c = 10$$ because $$ 19 \mid (143-10). $$
So I have two questions: how is it possible to substitute $11$ as $a$, as my book does not prove this nor mention it and I have a very hard time with proving things myself?
And is that last step (solving for $c$) a trial and error approach, as it seems to be that way?
Why does your book proceed this way? That's because congruences, like equalities, are compatible with addition and multiplication, i.e. $$a\equiv a',\quad b\equiv b'\pmod n\implies\begin{cases} a+b\equiv a'+b',\\ab\equiv a'b'\pmod n \end{cases}$$ As to the explicit value of $c$, it is not at all obtaind by trial and error, but by a plain old euclidean division of $143$ by $19$.