From what I gathered, the automorphisms are as follows:
$\iota$ (the identity map) $\sigma_2: \sqrt[4]{3} \rightarrow \sqrt[4]{9}$ (squaring map) $\sigma_3: \sqrt[4]{3} \rightarrow \sqrt[4]{27}$ (cubing map) $\sigma_i: i \rightarrow -i$ (complex conjugation map)
I'm not sure what other automorphisms are possible, since in general I can't send a real number to an imaginary number (swapping them would be a significant change).
$\text{Gal}(\mathbb{Q}(\sqrt[4]{3}, i))$ is of order 8, because this is the order of the extension. So we can send $\sqrt[4]{3}$ to any other root of $X^4-3$ and $i$ to any other root of $X^2+1$, as doing this gives us 8 possibilities. One can see the group is generated by $i \mapsto -i$ and $\sqrt[4]{3} \mapsto i\sqrt[4]{3}$(call them $\sigma_1$ and $\sigma_2$ respectively). Now identify $\sigma_1$ with the reflection element in $D_8$ and identify $\sigma_2$ with the generator of the rotation subgroup of $D_8$. You can check this is an isomorphism. You can also see it in a different way, by noticing that $<\sigma_1>$ acts on $<\sigma_2>$ by conjugation, which in this case results exactly in inversion. So the galois group is the semidirect product of these two subgroups, the one being isomorphic to $\mathbb{Z}_2$, the other with $\mathbb{Z}_4$, so it is the semidirect product of both with the inversion action, which is exactly isomorphic to $D_8$.