Here we have $K_5$ complete subgraph that gives $5^3 = 125$ spanning trees (using Cayley's formula).
Adding one vertex to arbitrary edge, gives me this graph for example.
Using Mathematica, it gives me 200 spanning trees. But I don't know how to get this number using simple combinatorics rules etc. What is the simplest method to get the number of spanning trees for this graph?
Thanks.


Each spanning tree of $K_5$ that contains the augmented edge corresponds to a spanning tree of the new graph with both of the new edges added. Each spanning tree of of $K_5$ that doesn’t contain the augmented edge corresponds to two spanning trees of the new graph, one each with each of the new edges added.
$K_5$ has $\binom52=10$ edges, and each spanning tree includes $4$ of them so, each edge is included in $\frac4{10}\cdot125=50$ of the spanning trees. Thus the new graph has $50+2\cdot75=200$ spanning trees.