It is possible to choose between three equally desirable outcomes by tossing a fair coin as follows:
Choose option 1 if the first head appears on an even toss
Choose option 2 if the first tail appears on an even toss
Choose option 3 if the first head and the first tail both appear on an odd toss
Note that option 1 and option 2 are mutually exclusive, because we must have a head or a tail on the first toss.
This works because the binary expansion $$\frac 13 =0.010101010101 \dots$$ has a $1$ in all the even places. Or equivalently because $$\frac 13=\frac 14+\frac1{16}+ \dots +\frac 1{4^n}+\dots$$
This is quite a simple procedure (though perhaps not as well known as it might be). I was pondering in the bath what might be the most convenient set of options if there were five or seven possibilities.
For example I can pick off two fifths using the binary expansion of $\frac 15$ with heads and tails, and use my procedure for thirds to do the remaining three fifths - so it is possible. But can one do fifths or sevenths without resort to this kind of recursive procedure?
Elevated from a comment, at request of OP:
To choose with equal probability among $q$ alternatives, interpret your sequence of heads and tails as a sequence of zeros and ones in the binary expansion of some number $x$ between zero and one; when you have enough of the binary expansion to be sure that $x$ lies between $(p-1)/q$ and $p/q$, choose the $p$th of the $q$ alternatives.