I was really upset while I was trying to explain for my daughter that $\frac 23$ is greater than $\frac 35$ and she always claimed that $(3$ is greater than $2$ and $5$ is greater than $3)$ then $\frac 35$ must be greater than $\frac 23$.
At this stage she can't calculate the decimal so that she can't realize that $(\frac 23 = 0.66$ and $\frac 35 = 0.6).$
She is $8$ years old.



The concept of "bigger denominator makes smaller fraction" is easily understood and explained to a toddler. Just show her 1/5th of a pie versus 1/3rd. Or explain that when you divide among more people, there is less per person. So you can explain why her explanation must be wrong without any reference to decimal expansion.
Because 3 is greater than 2, it follows that 3/3 is greater than 2/3. Because 3 is less than 5, it follows that 3/3 is greater than 3/5. Combining the two, we can compare a fraction with larger numerator and smaller denominator with one with smaller numerators and larger denominator. But when one has larger both numerator and denominator, we cannot make this comparison on this basis alone and need more information.
To your specific example, to see why 2/3 is greater than 3/5 without decimal expansions, a more detailed picture (slices of a pie) can work. Or arithmetic like cross multiply the inequality, though that may be above toddler level.