I have used the formula
\begin{align}p_0(x)&=1\\ p_1(x)&=x\\ p_2(x)&=\frac12(3x^2−1)\\ p_3(x)&=\frac12(5x^3−3x) \end{align}
$$2x^3-x^2-3x+2=Ap_3(x)+Bp_2(x)+Cp_1(x)+Dp_0(x)$$
EDIT-
\begin{align}&=\frac A2(5x^3−3x) + \frac B2(3x^2−1) + Cx +D \end{align}
but don't know how to continue after this.
Continuing from your steps, we compare the coefficients of each term on the L.H.S and R.H.S.
$$2x^3-x^2-3x+2=\dfrac A2(5x^3−3x) + \dfrac B2(3x^2−1) + Cx +D$$
So, $$ 2x^3-x^2-3x+2=\dfrac{5}{2}Ax^3+\dfrac{3}{2}Bx^2+(C-\dfrac{3}{2}A)x+(D-\dfrac{B}{2})$$
For the $x^3$ term, we have $\dfrac{5}{2}A=2 \Rightarrow A=\dfrac{4}{5}$
For the $x^2$ term, we have $\dfrac{3}{2}B=-1 \Rightarrow B=\dfrac{-2}{3}$
For the $x$ term, we have $C-\dfrac{3}{2}A=-3 \Rightarrow C-\dfrac{3}{2}\cdot\dfrac{4}{5}=-3 \Rightarrow C-\dfrac{6}{5}=-3 \Rightarrow C=\dfrac{6}{5}-3\Rightarrow C=\dfrac{-9}{5}$
For the constant term, we have $D-\dfrac{1}{2}B=2 \Rightarrow D-\dfrac{1}{2} \cdot \dfrac{(-2)}{3}=2 \Rightarrow D=2-\dfrac{1}{3} \Rightarrow D=\dfrac{5}{3}$