Given $L_1=\begin{cases}P_1: x-y+z=4\\ P_2: 2x+y-z=6 \end{cases}$
and $L_2=\begin{cases}P_1:x+y+z=4\\ P_2:2x+3y-z=6 \end{cases}$
$L_1$ and $L_2$ are the intersection lines of the given planes. Find the angle between the lines $L_1,L_2$
First in order to find the intersection lines between the respective planes it is enough to find to dots that belong to the intersection line, so for $L_1$: $$ P_1+P_2 \Rightarrow 3x=10 \Rightarrow x={10 \over 3} $$
Then: $$ 2 \cdot \frac{10}{3}+y-z=6 \Rightarrow y-z=-\frac{2}{3} $$ For $z=0$ and $z=1$ we get $y=-\frac{2}{3}$ and $y=\frac{1}{3}$ respectively so now can represent $L_1$ parametrically: $(\frac{10}{3},\frac{1}{3}, 10)+t(0,-1,0)$ where $t(0,-1,0)$ is the direction vector.
After identical calculations we can find $L_2: (0,\frac{10}{4}, \frac{3}{2})+t(\frac{10}{3}, 0,-\frac{2}{3})$.
Now we can calculate the angle of $L_1, L_2$ via scalar product: $$ \cos \theta=\frac{L_1 \cdot L_2}{\Vert{L_1}\Vert \cdot \Vert L_2 \Vert}=0 \Rightarrow \theta=90^{\circ} $$
I'm not sure that my answer is correct and I feel I'm missing something.
The idea to find direction vectors of both lines is fine, but it's a bit unclear to me how you (think you) arrive at these direction vectors...
You can either 'solve' both systems and from the parametric form of the two solution sets, you can simply read off the two direction vectors.
Alternatively, note that you can also simply read off the normal vectors of both planes in each system and the cross product of these normal vectors give you the respective direction vectors, so: $$\left( 1,-1,1 \right) \times \left( 2,1,-1 \right) = \left( 0,3,3 \right) \quad\mbox{and}\quad \left( 1,1,1 \right) \times \left( 2,3,-1 \right) = \left( -4,3,1 \right)$$ So you're looking for the angle between $\left( 0,3,3 \right)$ (or $\left( 0,1,1 \right)$, since you can scale!) and $\left( -4,3,1 \right)$.