Let be two samples collections A and B. Mean of the first is 5 and the second is 15. Standard deviation of the first is 2 and the second is 5.
Can we conclude something even though the two datasets have a different mean ?
Can we consider the ratio (standard deviation / mean) and conclude that A (0.4) is more widespread than B (0.33) ?
Your proposed ratio (std / mean) is called the coefficient of variation (http://en.wikipedia.org/wiki/Coefficient_of_variation). Since this is independent of the unit of measure of a sample/distribution, it is perfect for comparison of the dispersion.