This was in one of the examples of the textbook, but I couldn't figure out how they solved it. They say they multiply the left hand side by $\frac{n!}{n!}$ to get the right hand side:
$$ \frac{2^n \cdot (2n-3)!!}{n!} = 2\frac{(2n-2)!}{n!(n-1)!} $$
The double factorial stands for the product of all odd integers from 1 to 2$n$-3.
I've given this problem a lot of time, and I'm all out of ideas at this point.
Notice that $$2^n n! = 2(n) \cdot 2(n-1) \cdot 2(n-2) \cdots 2(2) \cdot 2(1) = (2n)(2n-2) \cdots (4)(2)$$
is the product of all even integers between $1$ and $2n$. So when you multiply the numerator and denominator by $n!$ you end up with
$$\dfrac{2n(2n-2)!}{n!n!}$$
since the even terms between $1$ and $2n-2$ interweave between the odd terms.
Cancelling the rogue $n$ on the numerator gives the result you seek.