How to understand the variance formula?

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How is the variance of Bernoulli distribution derived from the variance definition?

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PMF of the Bernoulli distribution is $$ p(x)=p^x(1-p)^{1-x}\qquad;\qquad\text{for}\ x\in\{0,1\}, $$ and the $n$-moment of a discrete random variable is $$ \text{E}[X^n]=\sum_{x\,\in\,\Omega} x^np(x). $$ Let $X$ be a random variable that follows a Bernoulli distribution, then \begin{align} \text{E}[X]&=\sum_{x\in\{0,1\}} x\ p^x(1-p)^{1-x}\\ &=0\cdot p^0(1-p)^{1-0}+1\cdot p^1(1-p)^{1-1}\\ &=0+p\\ &=p \end{align} and \begin{align} \text{E}[X^2]&=\sum_{x\in\{0,1\}} x^2\ p^x(1-p)^{1-x}\\ &=0^2\cdot p^0(1-p)^{1-0}+1^2\cdot p^1(1-p)^{1-1}\\ &=0+p\\ &=p. \end{align} Thus \begin{align} \text{Var}[X]&=\text{E}[X^2]-\left(\text{E}[X]\right)^2\\ &=p-p^2\\ &=\color{blue}{p(1-p)}, \end{align} or \begin{align} \text{Var}[X]&=\text{E}\left[\left(X-\text{E}[X]\right)^2\right]\\ &=\text{E}\left[\left(X-p\right)^2\right]\\ &=\sum_{x\in\{0,1\}} (x-p)^2\ p^x(1-p)^{1-x}\\ &=(0-p)^2\ p^0(1-p)^{1-0}+(1-p)^2\ p^1(1-p)^{1-1}\\ &=p^2(1-p)+p(1-p)^2\\ &=(1-p)(p^2+p(1-p)\\ &=\color{blue}{p(1-p)}. \end{align}

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IF $X \sim$ Bernoulli($p$), then what's the distribution of $X^2$? Find it, then find its expectation, that'll be $\mathbf{E}X^2$, and you already have $(\mathbf{E}X)^2$.

EDIT: the way it's done in the example you gave, it seems that they defined a different rv: $W = (X- \mathbf{E}X)^2$, which takes values $(0-p)^2$ and $(1-p)^2$ with corresponding probabilities.

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In a Bernoulli distribution, $E(X) = p$. Remember, the Bernoulli takes value $1$ with probability $p$ and $0$ with probability $1-p$, so the expectation of $X$ is $1\cdot p + 0\cdot (1-p) = p$. The expectation of any function of the Bernoulli is similarly $(E(g(x)) = g(1)\cdot p + g(0)\cdot(1-p)$ Thus $$ \begin{align} Var(X) &= E\left((X - E(X))^2\right)\\ &= \overbrace{\underbrace{(1-p)^2}_{g(1)}\cdot p}^\textrm{Bernoulli = 1; probability p} + \underbrace{\overbrace{(0-p)^2}^{g(0)}\cdot(1-p)}_{\textrm{Bernoulli = 0; probability (1-p)}}\\ \end{align} $$ The rest follows what you brought in the question