Someone is trying to introduce a new process in the production of a precision instrument for industrial use. The new process keeps the average weight but hopes to reduce the variability, which until now has been characterized by $\sigma^2 = 14.5$.
Because the complete introduction of the new process has costs, a test has been done and 16 instruments have been produced with this new method. For $\alpha = 0.05$ and knowing that the sample variance $s^2 > = 6.8$, what is the decision to take? Suppose that the universe can be considered approximately normal.
I have the population variance, so I can use the normal distribution. My hypothesis is
$$H_0 : \sigma ^2 = 14.5$$
The test value:
$$X^2_0 = \frac{15*6.8^2}{14.5^2}) = 3.2989 $$
$$X^2_{\alpha,n-1} = X^2_{0.05,15} = 25.00$$
$X^2_0 > X^2_{\alpha,n-1}$ is false, so I fail to reject H_0?
Because $\frac{(n-1)S^2}{\sigma^2} \sim \mathsf{Chisq}(\nu=n-1),$ a 95% confidence interval (CI) for $\sigma^2$ based on a sample variance $S^2$ is of the form $\left(\frac{(n-1)S^2}{U},\, \frac{(n-1)S^2}{U}\right),$ where $L$ and $U$ cut probability $0.025$ from the lower and upper tails of $\mathsf{Chisq}(\nu=n-1),$ respectively. [This confidence interval is based on the assumption that weights are normal.]
Thus a 95% CI for $\sigma^2$ based on $S^2 = 6.8$ for a normal sample of size $n = 16$ is $(3.71, 16.29).$ This CI represents non-rejectable values of $\sigma_0^2.$ [The computation is done below using R statistical software, but you can verify it using printed tables of the chi-squared distribution.]
Because $\sigma_0^2 = 14.5$ lies in the CI so you cannot reject $H_0: \sigma^2 = 14.5$ against $H_a: \sigma^2 \ne 14.5$ at the 5% level.
Can you find critical values for the test statistic $Q = \frac{(n-1)S^2}{\sigma_0^2},$ beyond which the null hypothesis would be rejected (in either direction)?
Notes: There is some confusion in your question: (1) You do not state null and alternative hypotheses, so it is not clear whether you are doing a one- or two-sided test. (2) You seem to be mixing up sample standard deviation $S$ with $S^2$---you are squaring $S^2.$
If you want a one-sided test, you need a one-sided CI, which gives an upper bound $(-\infty, 14.05),$ which does not contain $14.5.$
In this case, can you find a critical value for the test statistic $Q =\frac{(n-1)S^2}{\sigma_0^2},$ below which the null hypothesis $H_0: \sigma^2 = 14.5$ would be rejected in favor of the one-sided alternative $H_a: \mu < 14.5?$