Assume that $p,q,r,s$ are prime. If $$p^3q^2=r^2s^3,$$ then according to the fundamental theorem of arithmetic:
(i) $ \ q=s \ $
(ii) $ \ q >r \ $
(iii) $ \ p^3=s^2 \ $
(iv) $ \ p^3<s^2 \ $
Answer:
We have
$ p^3q^2=r^2s^3 \ \Rightarrow pppqq=rrsss \ ...........(1) $
If $ \ p=r=s \ $ , then from $ \ (1) $ , we get
$ rrsqq=rrsss \\ \Rightarrow qq=ss, \ \ (by \ \ left \ \ cancel) \\ \Rightarrow q=s $ ,
Thus option (i) is true.
what about the other options ?
According to the fundamental theorem of arithmetic we have that
$$ p^3q^2=r^2s^3 \implies p=s \,\land \, q=r$$
and then the implication is false for all the options but the options (i) is compatible with that for the particular case $p=s=q=r$ even if not true in general for the given condition.