How does finding out if the null space has only the zero vector prove one-to-one?
One-to-one means that there are distinct images for each distinct vector input.
$$\mathbb R^n \to \mathbb R^m$$
For each distinct vector in $\mathbb R^n$ we have a distinct vector in $\mathbb R^m$.
If we use Reduced row echelon form to solve a matrix A and each $x=(x_1,x_2,...x_n)$ equals $0$, then that shows that there is a unique solution, and that we have a linearly independence.
With what I know I am not making the connection here.
If $f(v)=f(w)$ then $f(v-w)=0$, so $v-w=0$.