Let $V$ be a smooth irreducible projective curve over an algebraically closed field $k$, embedded in some projective space $\mathbb{P}^n$, and let $[H]$ be the induced hyperplane divisor class on $V$.
Question. Suppose $D$ is an effective divisor on $V$ such that $D$ is in $[H]$. Is $D$ necessarily realised as the intersection divisor of some hyperplane?
It is quite straightforward to see that the intersection divisor of any hyperplane in general position is indeed in $[H]$ – this seems to be the whole point behind linear equivalence.
I can prove this for plane curves using Bézout's theorem: after all, if $H$ and $D$ are linearly equivalent, then $\deg H = \deg D$, and so if $H - D$ is the divisor of a rational function $h$, then it must be possible to find linear forms $F$ and $G$ such that $h = F / G$, and then $H = V (F)$ while $D = V (G)$. But what about the case where $n > 2$?
Your question is equivalent to the proposition that the linear system of hyperplane divisors of a smooth curve $V$ is complete. This is not true for $n\geq 3$, as the following example will show:
For any $n\geq 3$, consider $\sigma_n:\mathbb{P}^1\rightarrow \mathbb{P}^n$ defined by $[x,y]\mapsto[x^{n+1},x^ny,\cdots,\widehat{x^2y^{n-1}},xy^n,y^{n+1}]$, then $\sigma_n$ is an embedding (you can check this in affine coordinates), and $\sigma_n(\mathbb{P}^1)$ is a projection of degree $(n+1)$ rational normal curve in $\mathbb{P}^{n+1}$ to $\mathbb{P}^n$. Therefore, the linear system of hyperplane divisors of $\sigma_n(\mathbb{P}^1)$ is a codimension $1$ subspace of $|\mathcal{O}(n+1)|$, so it is not complete. To find such a divisor $D$, let $p=\sigma_n([1,0])$, $q=\sigma_n([0,1])$, let $D=(n-1)p+2q$, then $D$ is not a hyperplane divisor of $\sigma_n(\mathbb{P}^1)$.