Let $F = $ a finite field for example. Let $\Bbb{Q}[F]$ be a field ring, which is similar to a group ring except you have both operations extended homomorphically to the whole space, so that distributivity occurs naturally and you have a ring.
But we chose $\Bbb{Q}$ as our coefficient ring. Is $\Bbb{Q}[F]$ a field? It's sort of like a finite extension when $F$ is finite! Interesting. Since we're not declaring a parent space.
What both operations extended homorphically to all of $\Bbb{Z}[F]$ means is this:
$a = \sum_{f \in F} a_f f, \ b = \sum_{f \in F} b_f f$
Then since $\cdot$ and $+$ are homomorphic in each argument (via extending ring-homomorphically), we have:
$$ a + b = \sum_{f \in F} (a_f + b_f) f \\ a\cdot b = \sum_{f \in F} \sum_{gh = f} (a_gb_h) f $$
Similar to standard group ring stuff.
Suppose $F$ is a finite field of cardinality $p$. Assume that $\mathbb Q[F]$ is a field. Then $\mathbb Q[F]$ contains all $(p-1)$th roots of unity.
Also, $\mathbb Q$ embeds in $\mathbb Q[F]$, by the map $q \mapsto q \cdot 1_F$. Hence it is a number field of degree $p$. But it contains $\zeta_{p-1}$, so it contains a field of degree $\varphi(p-1)$. Hence $\varphi(p-1) \mid p$. This is not possible for $p \geq 5$.