I know that determining (semantic) entailment in propositional logic is decidable by the truth table method. For instance, let:
$\phi = b \rightarrow a \\ \psi = b \lor c \rightarrow a$
Then we can use the truth table method to determine whether $\phi$ entails $\sigma$, which is this case is true.
We can also (syntactically) derive $\psi$ from $\phi$, for instance by using natural deduction. However, is determining derivability decidable in propositional logic?
For systems that are both sound and complete (which for propositional logic is pretty much any system, that's out there ... it would be embarrassing for a logician to propose a proof system for propositional logic that would be not be both sound and complete), this is trivial: we would have $\Gamma \vdash \phi$ iff $\Gamma \vDash \phi$, and since the latter is decidable, the former is decidable as well.
If a proof system is not both sound and complete .... well, if a system is not sound and is in fact able to derive any statement from nothing, then derivability is also trivially decidable: everything is derivable!
For other systems yet ... Hmmm, I am actually unsure of the answer ... though I wonder if you could have some kind of bizarre propositional logic with which you can encode claims about Turing-machines and their behavior, and thus generate some kind of undecidability result ...